| WTT Contender - Rio - Damer - Kval | 2023/08/08 20:50 | Valentina Rios v Audrey Zarif | L | 0-3 |
| WTT Contender - Lima - Damer - Kval | 2023/08/01 22:10 | Eunhye Lee v Valentina Rios | L | 3-0 |
| Poland First league | 2023/03/13 19:55 | Valentina Rios v Ying Ying Chang | L | 1-3 |
| ITTF Pan American Championships - Damer | 2022/11/03 20:15 | Valentina Rios v Mo Zhang | L | 0-4 |
| ITTF Sydamerikanska mästerskapen - Damer | 2022/07/24 23:00 | Valentina Rios v Candela Molero | W | 3-1 |
| WTT Contender - Lima - Damer | 2022/06/16 16:15 | Valentina Rios v Miyu Nagasaki | L | 0-3 |
| WTT Contender - Lima - Damer - Kval | 2022/06/15 21:30 | Valentina Rios v Daniely Rios | W | 2-0 |
| WTT Contender - Lima - Damer - Kval | 2022/06/14 22:00 | Francesca Escobedo v Valentina Rios | W | 1-3 |
| WTT Feeder - Otocec - Damer | 2023/11/02 12:15 | Ana Tofant v Zdena Blaskova | L | 1-3 |
| Europe Cup - Damer | 2023/10/21 08:40 | Patricia Santos v Ana Tofant | L | 3-1 |
| Europe Cup - Damer | 2023/10/20 14:00 | Ana Tofant v Bianca Mei Rosu | L | 2-3 |
| Europe Cup - Damer | 2023/10/20 12:05 | Ana Tofant v Elena Zaharia | L | 0-3 |
| European Champions League - Damer | 2023/09/23 10:10 | Leili Mostafavi v Ana Tofant | L | 3-1 |
| European Champions League - Damer | 2023/09/22 14:25 | Ana Tofant v Natalia Partyka | W | 3-2 |
| Champions League - Damer | 2023/09/21 14:55 | Silvia Coll v Ana Tofant | W | 1-3 |
| Europeiska lagmästerskapen - Damer | 2023/09/12 12:20 | Ana Tofant v Hana Arapovic | L | 2-3 |