| WTT Feeder - Gaia - Damer - Kval | 11/22 16:40 | - | Valentina Rios v Ana Tofant | L | 1-3 | |
| WTT Contender - Rio - Damer - Kval | 08/08 20:50 | - | Valentina Rios v Audrey Zarif | L | 0-3 | |
| WTT Contender - Lima - Damer - Kval | 08/01 22:10 | - | Eunhye Lee v Valentina Rios | L | 3-0 | |
| Poland First league | 03/13 19:55 | - | Valentina Rios v Ying Ying Chang | L | 1-3 | |
| ITTF Pan American Championships - Damer | 11/03 20:15 | - | Valentina Rios v Mo Zhang | L | 0-4 | |
| ITTF Sydamerikanska mästerskapen - Damer | 07/24 23:00 | - | Valentina Rios v Candela Molero | W | 3-1 | |
| WTT Contender - Lima - Damer | 06/16 16:15 | 5 | Valentina Rios v Miyu Nagasaki | L | 0-3 | |
| WTT Contender - Lima - Damer - Kval | 06/15 21:30 | - | Valentina Rios v Daniely Rios | W | 2-0 | |
| WTT Contender - Lima - Damer - Kval | 06/14 22:00 | - | Francesca Escobedo v Valentina Rios | W | 1-3 | |
| Paraguay Open - U21 - Damer | 09/12 20:15 | - | Maki Shiomi v Valentina Rios | L | 3-0 | |
| Paraguay Open - Damer | 09/11 19:40 | - | Ana Codina v Valentina Rios | L | 3-0 | |
| Paraguay Open - U21 - Damer | 09/11 15:55 | - | Panambi Caceres v Valentina Rios | W | 1-3 |